Skip navigation

Non-targeted analysis reveals hundreds of per- and polyfluoroalkyl substances (PFAS) in UK freshwater in the vicinity of a fluorochemical plant

Non-targeted analysis reveals hundreds of per- and polyfluoroalkyl substances (PFAS) in UK freshwater in the vicinity of a fluorochemical plant

Megson, David, Niepsch, Daniel, Spencer, Jonathan, dos Santos, Claudio, Florance, Hannah, MacLeod, Cecilia ORCID: 0000-0002-4223-111X and Ross, Ian (2024) Non-targeted analysis reveals hundreds of per- and polyfluoroalkyl substances (PFAS) in UK freshwater in the vicinity of a fluorochemical plant. Chemosphere, 367:143645. ISSN 0045-6535 (Print), 1879-1298 (Online) (doi:https://doi.org/10.1016/j.chemosphere.2024.143645)

[img]
Preview
PDF (Open Access article)
48457 MACLEOD_Non-targeted_Analysis_Reveals_Hundreds_Of_Per-_And_Polyfluoroalkyl_Substances (PFAS)_In_UK_Freshwater_In_The_Vicinity_Of_A_Fluorochemical_Plant_(OA)_2024.pdf - Published Version
Available under License Creative Commons Attribution.

Download (5MB) | Preview

Abstract

There are now over 7 million recognised per- and polyfluoroalkyl substances (PFAS), however the majority of routine monitoring programmes and policy decisions are based on just a handful of these. There is need for a shift towards gaining a better understanding of the total PFAS present in a sample rather than relying on targeted analysis alone. Total PFAS methods help us to understand if targeted methods are missing a mass of PFAS, but they do not identify which PFAS are missing. Non- targeted methods fill this knowledge gap by using high resolution mass spectrometry to identify the PFAS present in a sample. In this manuscript we use complimentary targeted and non-targeted analysis (NTA) to detect hundreds of PFAS in five freshwater samples obtained from the Northwest of the UK. Targeted analysis revealed PFOA at a maximum concentration of 12,100 ng L-1 , over three orders of magnitude greater than the proposed environmental quality standard (EQS) of 100 ng L-1. A conservative assessment calculated an averag

Item Type: Article
Uncontrolled Keywords: per- and polyfluoroalkyl substance (PFAS), non-targeted screening (NTS), water, high resolution mass spectrometry
Subjects: Q Science > Q Science (General)
T Technology > T Technology (General)
T Technology > TP Chemical technology
Faculty / School / Research Centre / Research Group: Faculty of Engineering & Science
Faculty of Engineering & Science > School of Engineering (ENG)
Last Modified: 06 Nov 2024 13:14
URI: http://gala.gre.ac.uk/id/eprint/48457

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year

View more statistics