Egambaram, Orielia P., Murray, Alex T., Hiscock, Jennifer R. and Clark, Ewan R. ORCID: https://orcid.org/0000-0001-7287-2631 (2024) Reductive dehalogenation towards olefins mediated by phase-transfer electrocatalysis. Accounts and Rapid Communications in Chemical Synthesis (SYNLET). ISSN 0936-5214 (Print), 1437-2096 (Online) (doi:10.1055/a-2446-3355)

PDF (Author's Accepted Manuscript) 48684 CLARK_Reductive_Dehalogenation_Towards_Olefins_Mediated_By_Phase-Transfer_Electrocatalysis_(AAM)_2024.pdf - Accepted Version Restricted to Repository staff only until 5 November 2025. Download (550kB) | Request a copy

Abstract

Mild biphasic conditions enable dibutylviologen salts to act as both phase-transfer catalysts and electrocatalysts for the electroreduction of vicinal dibromides. Optimized experimental reaction conditions permit the production of the corresponding alkenes in competitive yields for a wide range of activated and nonactivated substrates, demonstrating good functional-group tolerance.

Item Type:	Article
Uncontrolled Keywords:	electrosynthesis, electrocatalysis, phase-transfer catalysis, viologens, alkenes
Subjects:	Q Science > Q Science (General) Q Science > QD Chemistry T Technology > TP Chemical technology
Faculty / School / Research Centre / Research Group:	Faculty of Engineering & Science Faculty of Engineering & Science > School of Science (SCI)
Last Modified:	25 Nov 2024 14:43
URI:	http://gala.gre.ac.uk/id/eprint/48684

Actions (login required)

View Item

Downloads