Kiaku, Cyrille, Walsh, Jamie M., Leech, Matthew C., Poole, Darren L., Mason, Joseph, Goodall, Iain C. A., Devo, Perry and Lam, Kevin ORCID: 0000-0003-1481-9212 (2023) Electrochemical isothiocyanation of primary amines. Organic Letters, 25 (7). pp. 1147-1150. ISSN 1523-7060 (Print), 1523-7052 (Online) (doi:https://doi.org/10.1021/acs.orglett.3c00128)

Preview	PDF (AAM) 38568_LAM_Electrochemical_isothiocyanation_of_primary_amines.pdf - Accepted Version Download (592kB) | Preview
Preview	PDF (Supporting Information) 38568_LAM_Electrochemical_isothiocyanation_of_primary_amines_SUPPORTING_INFORMATION.pdf - Supplemental Material Download (4MB) | Preview

Abstract

Isothiocyanates are ubiquitous building blocks used across the fields. Nevertheless, their classical syntheses very often rely on the use of toxic and expensive reagents. Herein, we report a new practical, mild, high-yielding, and supporting-electrolyte-free electrochemical method for the preparation of aliphatic and aromatic isothiocyanates from amine and carbon disulfide.

Item Type:	Article
Uncontrolled Keywords:	amines; desulfurization; disulfides; electrodes; salts, electrosynthesis
Subjects:	Q Science > Q Science (General) Q Science > QD Chemistry
Faculty / School / Research Centre / Research Group:	Faculty of Engineering & Science Faculty of Engineering & Science > School of Science (SCI)
Last Modified:	15 Feb 2024 01:38
URI:	http://gala.gre.ac.uk/id/eprint/38568

Actions (login required)

View Item

Downloads