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All-fullerene-based cells for nonaqueous redox flow batteries

All-fullerene-based cells for nonaqueous redox flow batteries

Friedl, Jochen, Lebedeva, Maria A., Porfyrakis, Kyriakos ORCID logoORCID: https://orcid.org/0000-0003-1364-0261, Stimming, Ulrich and Chamberlain, Thomas W. ORCID logoORCID: https://orcid.org/0000-0001-8100-6452 (2017) All-fullerene-based cells for nonaqueous redox flow batteries. Journal of the American Chemical Society, 140 (1). pp. 401-405. ISSN 0002-7863 (Print), 1520-5126 (Online) (doi:10.1021/jacs.7b11041)

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Abstract

Redox flow batteries have the potential to revolutionize our use of intermittent sustainable energy sources such as solar and wind power by storing the energy in liquid electrolytes. Our concept study utilizes a novel electrolyte system, exploiting derivatized fullerenes as both anolyte and catholyte species in a series of battery cells, including a symmetric, single species system which alleviates the common problem of membrane crossover. The prototype multielectron system, utilizing molecular based charge carriers, made from inexpensive, abundant, and sustainable materials, principally, C and Fe, demonstrates remarkable current and energy densities and promising long-term cycling stability.

Item Type: Article
Uncontrolled Keywords: fullerenes, redox flow batteries
Subjects: Q Science > QD Chemistry
Faculty / School / Research Centre / Research Group: Faculty of Engineering & Science
Faculty of Engineering & Science > School of Engineering (ENG)
Last Modified: 15 Oct 2019 11:50
URI: http://gala.gre.ac.uk/id/eprint/25575

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