Sinha, Sapna, Sheng, Yuewen, Griffiths, Ian, Young, Neil P., Zhou, Si, Kirkland, Angus I., Porfyrakis, Kyriakos ORCID: https://orcid.org/0000-0003-1364-0261 and Warner, Jamie H. (2018) In-Situ atomic level studies of Gd atom release and migration on graphene from a metallofullerene precursor. ACS Nano, 12 (10). pp. 10439-10451. ISSN 1936-0851 (Print), 1936-086X (Online) (doi:10.1021/acsnano.8b06057)

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Abstract

We show how Gd based metallofullerene (Gd3N@C80) molecules can be used to create single adatoms and nanoclusters on a graphene surface. An in-situ heating holder within an aberration corrected scanning transmission electron microscope is used to track the adhesion of endohedral metallofullerenes (MFs) to the surface of graphene, followed by Gd metal ejection and diffusion across the surface. Heating to 900oC is used to promote adatom migration and metal nanocluster formation, enabling direct imaging of the assembly of nanoclusters of Gd. We show that hydrogen can be used to reduce the temperature of MF fragmentation and metal ejection, enabling Gd nanocluster formation on graphene surfaces at temperatures as low as 300oC. The process of MF fragmentation and metal ejection is captured in-situ and reveals that after metal release, the C80 cage opens further and fuses with the surface monolayer carbon glass on graphene, creating a highly stable carbon layer for further Gd adatom adhesion. Small voids and defects (~1nm) in the surface carbon glass act as trapping sites for Gd atoms, leading to atomic self-assembly of 2D monolayer Gd clusters. These results show that MFs can adhere to graphene surfaces at temperatures well above their bulk sublimation point, indicating that the surface bound MFs have strong adhesion to dangling bonds on graphene surfaces. The ability to create dispersed single Gd adatoms, and Gd nanoclusters on graphene may have impact in spintronics and magnetism.

Item Type:	Article
Uncontrolled Keywords:	ADF-STEM, Gd, graphene, 2D materials, metallofullerenes, TEM
Subjects:	Q Science > QC Physics Q Science > QD Chemistry
Faculty / School / Research Centre / Research Group:	Faculty of Engineering & Science Faculty of Engineering & Science > School of Engineering (ENG)
Last Modified:	15 Oct 2019 11:50
URI:	http://gala.gre.ac.uk/id/eprint/25569

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