Skip navigation

MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration

MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration

Szilágyi, Petra Ágota, Lutz, Martin, Gascon, Jorge, Juan-Alcaniz, Jana, van Esch, Jan, Kapteijn, Freek, Geerlings, Hans, Dam, Bernard and van de Krol, Roel (2013) MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration. CrystEngComm, 15 (30). pp. 6003-6008. ISSN 1466-8033 (Online) (doi:https://doi.org/10.1039/c3ce40653a)

[img] PDF (Publisher's PDF)
14413_SZILAGYI_MOF@MOF_Core-shell_vs_Janus_Particles_2013.pdf - Published Version
Restricted to Repository staff only

Download (428kB)

Abstract

The effect of strain on core–shell MOFcore@MOFshell particles is discussed and compared with that observed for analogous Janus particles. Whereas Janus particles do not display any effect of strain, the core of fully coated core–shell particles collapsed upon the formation of the outer shell, leaving the core inaccessible for guest adsorption. This suggests that Janus particles might become ideal candidates for gas separation, while core–shell particles could play a key role in sequestration of guest molecules.

Item Type: Article
Uncontrolled Keywords: core-shell particles, Janus particles, metal-organic frameworks, strain, hydrogen storage
Faculty / School / Research Centre / Research Group: Faculty of Engineering & Science
Faculty of Engineering & Science > School of Science (SCI)
Last Modified: 15 Nov 2021 15:11
URI: http://gala.gre.ac.uk/id/eprint/14413

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year

View more statistics