Crystal structures of two palladacycles from the C-H activation of 2-(Thiophen-2-yl)pyridine
Callear, Samantha K., Spencer, John, Patel, Hiren, Deadman, John J. and Hursthouse, Michael B. (2011) Crystal structures of two palladacycles from the C-H activation of 2-(Thiophen-2-yl)pyridine. Journal of Chemical Crystallography, 41 (4). pp. 523-527. ISSN 1074-1542 (print) 1572-8854 (online) (doi:10.1007/s10870-010-9913-5)Full text not available from this repository.
A C,N-bound palladacycle dimer has been synthesised
by reaction of 2-(thiophen-2-yl)pyridine, LH, with
palladium acetate in acetic acid. Characterisation by single
crystal X-ray diffraction showed the palladacycle dimer,
[(L)Pd(OAc)]2, to crystallise in the monoclinic space
group P21/n with cell parameters a = 9.5853(1) A ° , b =
19.1332(3) A ° , c = 12.3889(2) A ° , b = 103.732(1)�. Reaction
of [(L)Pd(OAc)]2 with triphenylphosphine afforded a
trans-substituted monomeric complex, [(L)PdPPh3(OAc)]
which was also analysed using single crystal X-ray diffraction.
[(L)PdPPh3(OAc)] crystallises in the monoclinic space
group P21/c with cell parameters a = 9.4839(1) A ° ,
b = 11.0427(2) A ° , c = 26.0770(4) A ° , b = 95.022(1)�.
|Uncontrolled Keywords:||crystal structure, palladacycle, 2-(Thiophen-2-yl)pyridine, dimer, Triphenylphosphine|
|Subjects:||Q Science > QD Chemistry|
|School / Department / Research Groups:||School of Science|
School of Science > Department of Pharmaceutical, Chemical & Environmental Sciences
|Last Modified:||10 Jan 2013 13:58|
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