Callear, Samantha K., Spencer, John, Patel, Hiren, Deadman, John J. and Hursthouse, Michael B. (2010) Crystal structures of two palladacycles from the C-H activation of 2-(Thiophen-2-yl)pyridine. Journal of Chemical Crystallography, 41 (4). pp. 523-527. ISSN 1074-1542 (Print), 1572-8854 (Online) (doi:10.1007/s10870-010-9913-5)

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Abstract

A C,N-bound palladacycle dimer has been synthesised by reaction of 2-(thiophen-2-yl)pyridine, LH, with palladium acetate in acetic acid. Characterisation by single crystal X-ray diffraction showed the palladacycle dimer, [(L)Pd(OAc)]2, to crystallise in the monoclinic space group P21/n with cell parameters a = 9.5853(1) Å, b = 19.1332(3) Å, c = 12.3889(2) Å, β = 103.732(1)°. Reaction of [(L)Pd(OAc)]2 with triphenylphosphine afforded a trans-substituted monomeric complex, [(L)PdPPh3(OAc)] which was also analysed using single crystal X-ray diffraction. [(L)PdPPh3(OAc)] crystallises in the monoclinic space group P21/c with cell parameters a = 9.4839(1) Å, b = 11.0427(2) Å, c = 26.0770(4) Å, β = 95.022(1)°.

Item Type:	Article
Uncontrolled Keywords:	crystal structure, palladacycle, 2-(Thiophen-2-yl)pyridine, dimer, Triphenylphosphine
Subjects:	Q Science > QD Chemistry
Faculty / School / Research Centre / Research Group:	Faculty of Engineering & Science Faculty of Engineering & Science > School of Science (SCI)
Related URLs:	Publisher
Last Modified:	07 Dec 2016 16:06
URI:	http://gala.gre.ac.uk/id/eprint/5839

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