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Toluates: unexpectedly versatile reagents

Toluates: unexpectedly versatile reagents

Lam, Kevin ORCID: 0000-0003-1481-9212 and Markó, István E. (2009) Toluates: unexpectedly versatile reagents. Tetrahedron, 65 (52). pp. 10930-10940. ISSN 0040-4020 (doi:https://doi.org/10.1016/j.tet.2009.09.111)

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Abstract

The mechanism of the monoelectronic reduction of aromatic esters has been investigated. The unexpected synthetic utility of the toluate moiety in the deoxygenation of alcohols and the allylation of ketones is also reported. Finally, the use of aromatic esters as robust, though easily removable, protecting groups is depicted. © 2009 Elsevier Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: Reduction, Ester
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Faculty / Department / Research Group: Faculty of Engineering & Science
Faculty of Engineering & Science > Department of Pharmaceutical, Chemical & Environmental Sciences
Last Modified: 10 Oct 2017 16:36
Selected for GREAT 2016: None
Selected for GREAT 2017: None
Selected for GREAT 2018: None
Selected for GREAT 2019: None
URI: http://gala.gre.ac.uk/id/eprint/17710

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