Toluates: unexpectedly versatile reagents
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Lam, Kevin ORCID: https://orcid.org/0000-0003-1481-9212 and Markó, István E. (2009) Toluates: unexpectedly versatile reagents. Tetrahedron, 65 (52). pp. 10930-10940. ISSN 0040-4020 (doi:10.1016/j.tet.2009.09.111)
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Official URL: https://doi.org/10.1016/j.tet.2009.09.111
Abstract
The mechanism of the monoelectronic reduction of aromatic esters has been investigated. The unexpected synthetic utility of the toluate moiety in the deoxygenation of alcohols and the allylation of ketones is also reported. Finally, the use of aromatic esters as robust, though easily removable, protecting groups is depicted. © 2009 Elsevier Ltd. All rights reserved.
Item Type: | Article |
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Uncontrolled Keywords: | Reduction, Ester |
Subjects: | Q Science > QC Physics Q Science > QD Chemistry |
Faculty / School / Research Centre / Research Group: | Faculty of Engineering & Science Faculty of Engineering & Science > School of Science (SCI) |
Last Modified: | 10 Oct 2017 16:36 |
URI: | http://gala.gre.ac.uk/id/eprint/17710 |
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