King, Malcolm D., Sue, Rodney E., White, Rodney H. and Young, David J. (1997) The thermal desulfination of allylic sulfonyl halides. Tetrahedron Letters, 38 (25). pp. 4493-4496. ISSN 0040-4039 (doi:10.1016/S0040-4039(97)00911-8)

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Abstract

Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal
desulfination with allylic rearrangement to yield the corresponding allylic halides. The desulfination of a cyclic allylic sulfonyl bromide is stereospecific, proceeding with T-syn bromine migration.

Item Type:	Article
Additional Information:	[1] Accepted: 9 May 1997. [2] Available online: 26 March 1998. [3] First published in print: 23 June 1997.
Uncontrolled Keywords:	allylic sulfonyl halides, halogenolysis, triorganotin sulfinates, thermal desulfination, allylic halides, desulfination, cyclic allylic sulfonyl bromide, γ-syn bromine migration
Subjects:	Q Science > QA Mathematics > QA76 Computer software Q Science > QD Chemistry
Pre-2014 Departments:	School of Computing & Mathematical Sciences School of Computing & Mathematical Sciences > Computer & Computational Science Research Group
Related URLs:	Publisher Organisation
Last Modified:	14 Oct 2016 09:00
URI:	http://gala.gre.ac.uk/id/eprint/327

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