Spencer, John, Chowdhry, Babur Z., Mallet, Anthony I., Rathnam, Rajendra P., Adatia, Trushar, Bashall, Alan and Rominger, Frank (2008) C-H activations on a 1H-1,4-benzodiazepin-2(3H)-one template. Tetrahedron, 64 (26). pp. 6082-6089. ISSN 0040-4020 (doi:10.1016/j.tet.2008.01.059)

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Abstract

Air stable benzodiazepine containing palladacycles were synthesized by a C-H activation reaction and studied by mass spectrometry and X-ray crystallography. Catalytic C-H functionalizations of 1-methyl-5-phenyl-1H-1,4-benzodiazepin-2(3H)-one with diphenyliodonium hexafluorophosphate led to a mixture, which included the starting material and the expected product 1-methyl-5-(2'-biphenyl)-1H-1,4-benzodiazepin-2(3H)-one.

Item Type:	Article
Additional Information:	[1] Available first online on 25 January 2008. [2] Published in Tetrahedron, Volume 64, (23 June 2008) - Catalytic Aromatic C-H Activation.
Uncontrolled Keywords:	benzodiazepine, C-H activation, palladium, catalysis
Subjects:	Q Science > QD Chemistry
Faculty / School / Research Centre / Research Group:	Faculty of Engineering & Science > School of Science (SCI)
Related URLs:	http://www.elsevier.com/locate/tet Organisation Organisation
Last Modified:	21 Feb 2020 15:54
URI:	http://gala.gre.ac.uk/id/eprint/2221

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