Paul, Alison, Fallis, Ian A., Stokes, Emily C., King, Stephen M. and Griffiths, Peter ORCID: 0000-0002-6686-1271 (2018) Structural evolution in metallomicroemulsions – the effect of increasing alcohol hydrophobicity. Dalton Transactions. pp. 1-7. ISSN 1477-9226 (Print), 1477-9234 (Online) (doi:https://doi.org/10.1039/C8DT02031K)

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Abstract

Small-angle neutron scattering and contrast variation has been employed to quantify how a series of alcohols with increasing hydrophobicity exert different abilities to structure a model toluene based metallomicroemulsion – a microemulsion system stabilised with a metallosurfactant. Classical microemulsion phase evolution and droplet structure are observed, leading to an oil rich core stabilised by a surfactant film containing a highly concentrated, hydrated metal ion layer.

Item Type:	Article
Uncontrolled Keywords:	SANS, metallomicroemulsion
Subjects:	Q Science > QD Chemistry
Faculty / School / Research Centre / Research Group:	Faculty of Engineering & Science Faculty of Engineering & Science > School of Science (SCI)
Last Modified:	06 Apr 2020 17:25
URI:	http://gala.gre.ac.uk/id/eprint/21095

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