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Tuneable mechanical properties in low molecular weight gels

Tuneable mechanical properties in low molecular weight gels

Chen, Lin, Raeburn, Jaclyn, Sutton, Sam, Spiller, David G., Williams, James, Sharp, James S., Griffiths, Peter C. ORCID logoORCID: https://orcid.org/0000-0002-6686-1271, Heenan, Richard K., King, Stephen M., Paul, Alison, Furzeland, Steve, Atkins, Derek and Adams, Dave J. (2011) Tuneable mechanical properties in low molecular weight gels. Soft Matter, 7 (20). pp. 9721-9727. ISSN 1744-683X (Print), 1744-6848 (Online) (doi:10.1039/C1SM05827D)

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Abstract

The mechanical properties of gels are critical to the final targeted applications. Depending on the application, different properties may be required. Here, we show that the mechanical strength and ability to recover of gels formed using a low molecular weight gelator can be controlled by two independent factors (i) the volume fraction of co-solvent (in this case DMSO) in the system and (ii) the temperature cycle used. These differences correlate with the large scale structure of the network that is formed from the self-assembled fibres. This opens up the potential to prepare gels with very different properties at the same final conditions, allowing the effect of microstructure to be probed.

Item Type: Article
Additional Information: [1] This article is part of themed collection: Biomimetic soft matter.
Uncontrolled Keywords: mechanical properties, gels
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Faculty / School / Research Centre / Research Group: Faculty of Engineering & Science
Faculty of Engineering & Science > School of Science (SCI)
Last Modified: 17 Feb 2020 15:56
URI: http://gala.gre.ac.uk/id/eprint/10169

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