C-H activations on a 1H-1,4-benzodiazepin-2(3H)-one template
Spencer, John, Chowdhry, Babur Z., Mallet, Anthony I., Rathnam, Rajendra P., Adatia, Trushar, Bashall, Alan and Rominger, Frank (2008) C-H activations on a 1H-1,4-benzodiazepin-2(3H)-one template. Tetrahedron, 64 (26). pp. 6082-6089. ISSN 0040-4020 (doi:10.1016/j.tet.2008.01.059)Full text not available from this repository.
Air stable benzodiazepine containing palladacycles were synthesized by a C-H activation reaction and studied by mass spectrometry and X-ray crystallography. Catalytic C-H functionalizations of 1-methyl-5-phenyl-1H-1,4-benzodiazepin-2(3H)-one with diphenyliodonium hexafluorophosphate led to a mixture, which included the starting material and the expected product 1-methyl-5-(2'-biphenyl)-1H-1,4-benzodiazepin-2(3H)-one. (C) 2008 Elsevier Ltd. All rights reserved.
|Additional Information:|| Available first online on 25 January 2008.  Published in Tetrahedron, Volume 64, (23 June 2008) - Catalytic Aromatic C-H Activation.|
|Uncontrolled Keywords:||benzodiazepine, C-H activation, palladium, catalysis|
|Subjects:||Q Science > QD Chemistry|
|Faculty / Department / Research Groups:||Faculty of Engineering & Science > Department of Pharmaceutical, Chemical & Environmental Sciences|
|Last Modified:||09 Dec 2016 12:23|
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