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Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks

Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks

Coupry, D. E., Butson, J., Petkov, P. S., Saunders, M., O'Donnell, K., Buckley, C., Addicoat, M., Heine, T. and Szilágyi, P. A. (2016) Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks. Chemical Communications, 52 (29). pp. 5175-5178. ISSN 1359-7345 (Print), 1364-548X (Online) (doi:10.1039/c6cc00659k)

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Abstract

A combined theoretical and experimental approach demonstrates that nanocluster embedment into the pores of metal-organic frameworks (MOF) may be influenced by the chemical functionalisation of the MOF. Furthermore, this results in the surface functionalisation of the embedded nanoclusters, highlighting the potential of MOF scaffolds for the design and synthesis novel functional materials.

Item Type: Article
Additional Information: Awarded Royal Society of Chemistry "Gold for Gold" Open Access voucher (code: Au-039449).
Uncontrolled Keywords: nanoclusters; metal-organic frameworks; surface functionalisation
Faculty / Department / Research Group: Faculty of Engineering & Science > Department of Pharmaceutical, Chemical & Environmental Sciences
Last Modified: 11 Apr 2017 08:48
Selected for GREAT 2016: GREAT a
Selected for GREAT 2017: None
Selected for GREAT 2018: None
URI: http://gala.gre.ac.uk/id/eprint/14417

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