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Synthesis and EPR studies of the first water-soluble N@C60 derivative

Synthesis and EPR studies of the first water-soluble N@C60 derivative

Cornes, Stuart P. ORCID: 0000-0002-8183-4060, Zhou, Shen and Porfyrakis, Kyriakos ORCID: 0000-0003-1364-0261 (2017) Synthesis and EPR studies of the first water-soluble N@C60 derivative. Chemical Communications, 53 (95). pp. 12742-12745. ISSN 1359-7345 (Print), 1364-548X (Online) (doi:https://doi.org/10.1039/c7cc07106j)

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Abstract

The first water-soluble derivative of the paramagnetic endohedral fullerene N@C60 has been prepared through the covalent attachment of a single addend containing two permethylated ╬▓cyclodextrin units to the surface of the carbon cage. The line width of the derivatives EPR signal is highly sensitive to both the nature of the solvent and the presence of Cu(II) ions in solution.

Item Type: Article
Uncontrolled Keywords: water soluble fullerenes, N@C60, synthesis
Subjects: Q Science > QD Chemistry
Faculty / Department / Research Group: Faculty of Engineering & Science
Faculty of Engineering & Science > School of Engineering (ENN)
Last Modified: 23 Oct 2019 10:51
Selected for GREAT 2016: None
Selected for GREAT 2017: None
Selected for GREAT 2018: None
Selected for GREAT 2019: None
URI: http://gala.gre.ac.uk/id/eprint/25769

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