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Finding the proton in a key intermediate of anti-Markovnikov alkyne hydration by a bifunctional catalyst

Finding the proton in a key intermediate of anti-Markovnikov alkyne hydration by a bifunctional catalyst

Grotjahn, Douglas B., Kragulj, Elijah J., Zeinalipour-Yazdi, Constantinos D. ORCID: 0000-0002-8388-1549, Miranda-Soto, Valentin, Lev, Daniel A. and Cooksy, Andrew L. (2008) Finding the proton in a key intermediate of anti-Markovnikov alkyne hydration by a bifunctional catalyst. Journal of the American Chemical Society, 130 (33). pp. 10860-10861. ISSN 0002-7863 (doi:https://doi.org/10.1021/ja803106z)

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Abstract

The secondary structure of a bifunctional catalyst positions a crucial reactive proton in the final intermediate of anti-Markovnikov alkyne hydration to give an aldehyde. NMR coupling and isotopic labeling studies elucidate the location of this proton and its involvement in hydrogen bonding.

Item Type: Article
Uncontrolled Keywords: anti-Markovnikov, alkyne hydration, bifunctional catalyst
Subjects: Q Science > QD Chemistry
Faculty / Department / Research Group: Faculty of Engineering & Science
Faculty of Engineering & Science > Department of Pharmaceutical, Chemical & Environmental Sciences
Last Modified: 09 Oct 2018 16:21
Selected for GREAT 2016: None
Selected for GREAT 2017: None
Selected for GREAT 2018: None
URI: http://gala.gre.ac.uk/id/eprint/21453

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