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Metal[BOND]metal bond formation between [n]metallocenophanes: Synthesis and characterisation of a dicarba[2]ruthenocenophanium dimer

Metal[BOND]metal bond formation between [n]metallocenophanes: Synthesis and characterisation of a dicarba[2]ruthenocenophanium dimer

Russell, Andrew D., Gilroy, Joe B., Lam, Kevin ORCID: 0000-0003-1481-9212, Haddow, Mairi F., Harvey, Jeremy N., Geiger, William E. and Manners, Ian (2012) Metal[BOND]metal bond formation between [n]metallocenophanes: Synthesis and characterisation of a dicarba[2]ruthenocenophanium dimer. Chemistry - A European Journal, 18 (26). pp. 8000-8003. ISSN 0947-6539 (Print), 1521-3765 (Online) (doi:https://doi.org/10.1002/chem.201201129)

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Abstract

Feeling the strain: The first example of metal-metal bonding between strained nmetallocenophanes is reported. A dicarba2ruthenocenophanium dimer has been synthesised through the oxidation of a dicarba2ruthenocenophane (see figure). The structural and electrochemical characterisation of the dimer is also discussed.

Item Type: Article
Uncontrolled Keywords: Dimerisation, Electrochemistry, Metal-metal bonding, Metallocenophanes, Strained compounds
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Faculty / Department / Research Group: Faculty of Engineering & Science
Faculty of Engineering & Science > Department of Pharmaceutical, Chemical & Environmental Sciences
Last Modified: 10 Oct 2017 14:52
Selected for GREAT 2016: None
Selected for GREAT 2017: None
Selected for GREAT 2018: None
URI: http://gala.gre.ac.uk/id/eprint/17716

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