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An anodic method for covalent attachment of molecules to electrodes through an ethynyl linkage

An anodic method for covalent attachment of molecules to electrodes through an ethynyl linkage

Sheridan, Matthew V., Lam, Kevin ORCID: 0000-0003-1481-9212 and Geiger, William E. (2013) An anodic method for covalent attachment of molecules to electrodes through an ethynyl linkage. Journal of the American Chemical Society, 135 (8). pp. 2939-2942. ISSN 0002-7863 (Print), 1520-5126 (Online) (doi:https://doi.org/10.1021/ja312405h)

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Abstract

Electroactive organometallic molecules have been covalently attached to electrode surfaces through an ethynyl linkage. The process takes advantage of ethynyl-based radicals generated by anodic oxidation of a lithio-activated terminal ethynyl group. Electrophores containing redox-active ferrocene, cymantrene, or cobaltocenium moieties have been deposited at the one-to-three monolayer level. Both metal-based and ligand-based chemical reactions have been carried out on the surface-modified systems.

Item Type: Article
Uncontrolled Keywords: Surface modification
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Faculty / Department / Research Group: Faculty of Engineering & Science
Faculty of Engineering & Science > Department of Pharmaceutical, Chemical & Environmental Sciences
Last Modified: 10 Oct 2017 14:06
Selected for GREAT 2016: None
Selected for GREAT 2017: None
Selected for GREAT 2018: None
Selected for GREAT 2019: None
URI: http://gala.gre.ac.uk/id/eprint/17715

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