Dunn, Jonathan, Motevalli, Majid and Dobbs, Adrian P. ORCID: 0000-0002-7241-7118 (2011) Donor cyclopropanes in synthesis: utilising silylmethylcyclopropanes to prepare 2,5-disubstituted tetrahydrofurans. Tetrahedron Letters, 52 (51). pp. 6974-6977. ISSN 0040-4039 (doi:https://doi.org/10.1016/j.tetlet.2011.10.091)

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Abstract

The use of donor-only silylmethylcyclopropanes in the Lewis acid promoted reaction with aldehydes to generate 2,5-disubstituted tetrahydrofurans is described. The diastereoselectivity obtained in the product is very much dependent upon the temperature of the reaction.

Item Type:	Article
Uncontrolled Keywords:	silylmethylcyclopropane, donor cyclopropane, 2,5-Disubstituted tetrahydrofuran
Subjects:	Q Science > QD Chemistry
Faculty / School / Research Centre / Research Group:	Faculty of Engineering & Science > School of Science (SCI)
Related URLs:	Publisher Organisation
Last Modified:	21 Oct 2020 22:31
URI:	http://gala.gre.ac.uk/id/eprint/9980

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