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The thermal desulfination of allylic sulfonyl halides

The thermal desulfination of allylic sulfonyl halides

King, Malcolm D., Sue, Rodney E., White, Rodney H. and Young, David J. (1997) The thermal desulfination of allylic sulfonyl halides. Tetrahedron Letters, 38 (25). pp. 4493-4496. ISSN 0040-4039 (doi:10.1016/S0040-4039(97)00911-8)

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Abstract

Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal
desulfination with allylic rearrangement to yield the corresponding allylic halides. The desulfination of a cyclic allylic sulfonyl bromide is stereospecific, proceeding with T-syn bromine migration.

Item Type: Article
Additional Information: [1] Accepted: 9 May 1997. [2] Available online: 26 March 1998. [3] First published in print: 23 June 1997.
Uncontrolled Keywords: allylic sulfonyl halides, halogenolysis, triorganotin sulfinates, thermal desulfination, allylic halides, desulfination, cyclic allylic sulfonyl bromide, γ-syn bromine migration
Subjects: Q Science > QA Mathematics > QA76 Computer software
Q Science > QD Chemistry
Pre-2014 Departments: School of Computing & Mathematical Sciences
School of Computing & Mathematical Sciences > Computer & Computational Science Research Group
Related URLs:
Last Modified: 14 Oct 2016 09:00
Selected for GREAT 2016: None
Selected for GREAT 2017: None
Selected for GREAT 2018: None
URI: http://gala.gre.ac.uk/id/eprint/327

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