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C–H activations on a 1H-1,4-benzodiazepin-2(3H)-one template

C–H activations on a 1H-1,4-benzodiazepin-2(3H)-one template

Spencer, John, Chowdhry, Babur Z., Mallet, Anthony I., Rathnam, Rajendra P., Adatia, Trushar, Bashall, Alan and Rominger, Frank (2008) C–H activations on a 1H-1,4-benzodiazepin-2(3H)-one template. Tetrahedron, 64 (26). pp. 6082-6089. ISSN 0040-4020 (doi:10.1016/j.tet.2008.01.059)

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Abstract

Air stable benzodiazepine containing palladacycles were synthesized by a C–H activation reaction and studied by mass spectrometry and X-ray crystallography. Catalytic C–H functionalizations of 1-methyl-5-phenyl-1H-1,4-benzodiazepin-2(3H)-one with diphenyliodonium hexafluorophosphate led to a mixture, which included the starting material and the expected product 1-methyl-5-(2′-biphenyl)-1H-1,4-benzodiazepin-2(3H)-one.

Item Type: Article
Uncontrolled Keywords: Benzodiazepine, C–H activation, Palladium, Catalysis
Subjects: Q Science > QD Chemistry
Pre-2014 Departments: School of Science
Last Modified: 14 Oct 2016 09:25
Selected for GREAT 2016: None
Selected for GREAT 2017: None
Selected for GREAT 2018: None
URI: http://gala.gre.ac.uk/id/eprint/10395

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